Place the sugar, syrup, and vinegar in a heavy pot and bring to a boil over medium heat.
Reduce the heat enough to keep the liquids simmering.
Remove the pot from the heat after 10-15 minutes - it has to be caramelized, not burnt.
Immediately add the Prosecco, Select or Aperol, and orange juice and stir vigorously. Be careful: it will splatter a bit.
Dip and swirl the apples into the caramel while it is still hot.
Display the apples over waxed paper and let them cool for 5 minutes.
Dip the bottom of each apple in the orange zest and return to cool completely.
Serve immediately or refrigerate for up to five days.